Journal article
Scandium chloride, alkyl and phenyl complexes of diamido-donor ligands
- Abstract:
-
Reactions of the lithiated diamido-pyridine and -amine ligands Li2N2TMSNpy or Li2N2NC2,TMS with ScCl3 in tetrahydrofuran (THF) afforded the five-coordinate scandium chloride derivatives [Sc(N2TMSNpy)Cl(THF)] 1 and [Sc(N2NC2,TMS)Cl(THF)] 2 where N2TMSNpy = MeC(2-C5H4N)(CH2NSiM3)2 and N2NC2,TMS = Me3SiN-(CH2CH2NSiMe3)2. The corresponding reactions of ScCl3 with the dilithium salts of the amino N-methylated two-carbon analogue N2NC2,Me (N2NC2,Me = MeN(CH2CH2NSiMe3)2) or of the amino N-silylated ...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
- Issue:
- 24
- Pages:
- 4649-4657
- Publication date:
- 2002-01-01
- DOI:
- EISSN:
-
1364-5447
- ISSN:
-
1472-7773
Item Description
- Language:
- English
- Pubs id:
-
pubs:51213
- UUID:
-
uuid:6ae003c5-2da7-463e-94d5-061962bf8b92
- Local pid:
- pubs:51213
- Source identifiers:
-
51213
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2002
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