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High pressure crystal structure and electrical properties of a single component molecular crystal [Ni(dddt)2] (dddt = 5,6-dihydro-1,4-dithiin-2,3-dithiolate)

Abstract:

Single-component molecular conductors form an important class of materials showing exotic quantum phenomena, owing to the range of behavior they exhibit under physical stimuli. We report the effect of high pressure on the electrical properties and crystal structure of the single-component crystal [Ni(dddt)2] (where dddt = 5,6-dihydro-1,4-dithiin-2,3-dithiolate). The system is isoelectronic and isostructural with [Pd(dddt)2], which is the first example of a single-comp...

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Publication status:
Published
Peer review status:
Peer reviewed

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Role:
Author
ORCID:
0000-0001-9063-9278
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Inorganic Chemistry
Department:
INORGANIC CHEMISTRY
Role:
Author
ORCID:
0000-0003-1629-6275
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Name:
Leverhulme Trust
Grant:
RPG-2015-292
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Name:
Japan Society for the Promotion of Science
Grant:
JP16H06346
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Name:
Samuel and Violette Glasstone Bequest
Publisher:
MDPI
Journal:
Molecules More from this journal
Volume:
24
Issue:
10
Article number:
1843
Publication date:
2019-05-14
Acceptance date:
2019-05-10
DOI:
EISSN:
1420-3049
ISSN:
1420-3049
Pmid:
31091658
Language:
English
Keywords:
Pubs id:
pubs:1003188
UUID:
uuid:6a70b619-dfd9-4274-94b0-9965663937a4
Local pid:
pubs:1003188
Source identifiers:
1003188
Deposit date:
2019-08-07

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