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PHOTOFRAGMENTATION VOLTAMMETRY STUDIES OF THE AMINOCARBENE COMPLEXES [(ETA(5)-C5H5)FE(CO)(L)(=C(NHR(1))(R(2))]BF4 [L = PPH3, P(P-TOL)3, R(1) = ME, CH2PH, R(2) = ME, BU]

Abstract:
The synthesis of the complexes [(η5-C5H5)Fe(CO)(L){=C(NHR 1)(R2)}]BF4 [L = PPh3, P(p-Tol)3; R1 = Me, CH2Ph; R2 = Me, Bu] is described. Photofragmentation voltammetry is used to demonstrate that the primary photoprocess is loss of the phosphine ligand in all four carbene complexes. A common intermediate is observed when the analogous aminocarbenes are studied.
Publication status:
Published

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Publisher copy:
10.1039/p29930001603

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Issue:
9
Pages:
1603-1609
Publication date:
1993-09-01
DOI:
EISSN:
1364-5471
ISSN:
0300-9580
Source identifiers:
44290
Language:
English
UUID:
uuid:6a386a49-eb78-4740-bdc5-8b5117f4355c
Local pid:
pubs:44290
Deposit date:
2012-12-19

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