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Journal article

The influence of catechol structure on the suicide-inactivation of tyrosinase.

Abstract:
3,6-Difluorocatechol, which cannot act as a monooxygenase tyrosinase substrate, is an oxidase substrate, and, in contrast to other catechols, oxidation does not lead to suicide-inactivation, providing experimental evidence for an inactivation mechanism involving reductive elimination of Cu(0) from the active site.
Publication status:
Published

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Publisher copy:
10.1039/b910500j

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Journal:
Organic and biomolecular chemistry
Volume:
7
Issue:
17
Pages:
3388-3390
Publication date:
2009-09-05
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
URN:
uuid:69fb535f-bc5f-409f-ba03-8d6760f0d531
Source identifiers:
132178
Local pid:
pubs:132178

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