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Non-linear sweep voltammetry of adsorbed species: theory and a method to determine formal potentials

Abstract:

Recent literature revealed the hitherto unexploited opportunities offered by unconventional cyclic voltammetry with non-triangular potential sweeps. We here investigate the implications of such techniques for the equilibrium voltammetry of surface-bound analytes and expose rather counter-intuitive effects: if only slightly different potential waveforms are applied, distinct and characteristic features arise in the voltammogram that can be readily exploited for quantitative analysis. Our work ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/C7CP04658H

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Chemistry; Physical & Theoretical Chem
Role:
Author
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Name:
European Research Council
Grant:
320403
Publisher:
Royal Society of Chemistry
Journal:
Physical Chemistry Chemical Physics More from this journal
Volume:
19
Issue:
42
Pages:
28820-28823
Publication date:
2017-10-11
Acceptance date:
2017-10-11
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Pubs id:
pubs:738275
UUID:
uuid:69c66c2d-f00b-4061-99e5-c4a693b3ff6f
Local pid:
pubs:738275
Source identifiers:
738275
Deposit date:
2017-10-24

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