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Can cyclic voltammetry at microdisc electrodes be approximately described by one-dimensional diffusion?

Abstract:

Fast scan cyclic voltammetry using microdisc electrodes is now widely employed for the study of the kinetics and mechanism of electrode processes. For convenience, it is common for experimentalists to interpret the results assuming that the disc can be treated as either a planar or a hemispherical electrode. Both approximations are available in the now widely adopted one-dimensional simulation package DigiSim which can simulate the cyclic voltammetric response of arbitrarily complex reaction ...

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Publication status:
Published

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Publisher copy:
10.1021/jp962323g

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY B More from this journal
Volume:
101
Issue:
6
Pages:
949-958
Publication date:
1997-02-06
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
UUID:
uuid:6952be5c-46f2-4a07-ae87-0b703ac0d31e
Local pid:
pubs:45455
Source identifiers:
45455
Deposit date:
2012-12-19

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