Journal article
A DIRECT RELATIONSHIP BETWEEN E=TI-L BOND-ANGLE AND TI=E BOND-LENGTH CAN EXIST IN [TI(E)L(4)] COMPLEXES (E=ORGANOIMIDO OR OXO)
- Abstract:
- Evidence for a 'direct' relationship between E=Ti-L bond angle and Ti=E bond length in five-coordinate complexes [Ti(E)L4] (E=organoimido or oxo) is presented and is supported by extended-Hückel molecular orbital calculations; the crystal structure of [Ti(tmtaa)(NC6H 3Me2-2,6)] is described (H2tmtaa= tetramethyldibenzotetraaza[14]annulene).
- Publication status:
- Published
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- Publisher copy:
- 10.1039/c39950002357
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Authors
Bibliographic Details
- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
- Issue:
- 22
- Pages:
- 2357-2359
- Publication date:
- 1995-11-21
- DOI:
- ISSN:
-
0022-4936
- Source identifiers:
-
51475
Item Description
- Language:
- English
- Pubs id:
-
pubs:51475
- UUID:
-
uuid:6944df61-31d9-42ea-b891-5f445705547d
- Local pid:
- pubs:51475
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 1995
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