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Adding water to sugar: a spectroscopic and computational study of alpha- and beta-phenylxyloside in the gas phase.

Abstract:

The gas phase structures of phenyl alpha- and beta-d-xylopyranoside (alpha- and beta-pXyl) and their mono-hydrates have been investigated using a combination of resonant two-photon ionization (R2PI), ultra-violet hole-burning and resonant infrared ion dip spectroscopy, coupled with density functional theory (DFT) and ab initio computation. The hole-burning experiments indicate the population of a single conformer only, in each of the two anomers. Their experimental and calculated infrared spe...

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Publication status:
Published

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Publisher copy:
10.1039/b504230e

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Journal:
Physical chemistry chemical physics : PCCP
Volume:
7
Issue:
12
Pages:
2474-2480
Publication date:
2005-06-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:68b86656-ff49-44aa-a649-25434f29a008
Source identifiers:
33139
Local pid:
pubs:33139
Language:
English

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