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Hydrodynamics and mass transport in wall-tube and microjet electrodes: An experimental evaluation of current theory

Abstract:

The application of steady-state and fast-scan linear sweep voltammetry to a high-speed wall-tube electrode (HWTE) is reported in different solvents to investigate the response of the HWTE over a wide range of Reynolds' numbers (Re). Experiments are reported for the oxidation of N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD) in propylene carbonate (PC), water, butyronitrile (BN), acetonitrile (AN), and acetonitrile-water mixture solutions containing 0.10 M supporting electrolyte for a 24 μm r...

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Publication status:
Published

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Publisher copy:
10.1021/jp030883r

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY B More from this journal
Volume:
107
Issue:
49
Pages:
13649-13660
Publication date:
2003-12-11
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Language:
English
Pubs id:
pubs:38878
UUID:
uuid:689e4f39-b322-4d6d-a47c-4c5e44661165
Local pid:
pubs:38878
Source identifiers:
38878
Deposit date:
2012-12-19

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