Journal article
Effects of convergent diffusion and charge transfer kinetics on the diffusion layer thickness of spherical micro- and nanoelectrodes.
- Abstract:
-
Nuances of the linear diffusion layer approximation are examined for slow charge transfer reactions at (hemi)spherical micro- and nanoelectrodes. This approximation is widely employed in Electrochemistry to evaluate the extent of electrolyte solution perturbed by the electrode process, which is essential to the understanding of the effects arising from thin-layer diffusion, convergent diffusion, convection, coupled chemical reactions and the double layer. The concept was well established for ...
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- Publication status:
- Published
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- Publisher copy:
- 10.1039/c3cp50290b
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Authors
Bibliographic Details
- Journal:
- Physical chemistry chemical physics : PCCP
- Volume:
- 15
- Issue:
- 19
- Pages:
- 7106-7113
- Publication date:
- 2013-05-05
- DOI:
- EISSN:
-
1463-9084
- ISSN:
-
1463-9076
- URN:
-
uuid:68505481-151f-4f19-abc4-2384b692819c
- Source identifiers:
-
394907
- Local pid:
- pubs:394907
Item Description
- Language:
- English
Terms of use
- Copyright date:
- 2013
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