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Switchable, reagent-controlled diastereodivergent photocatalytic carbocyclisation of imine-derived α-amino radicals

Abstract:

A reagent-controlled stereodivergent carbocyclisation of aryl aldimine-derived, photocatalytically-generated, α-amino radicals possessing adjacent conjugated alkenes, affording either bicyclic or tetracyclic products, is described. Under net reductive conditions using commercial Hantzsch ester, the α-amino radical species underwent a single stereoselective cyclisation to give trans-configured amino-indane structures in good yield, whereas using a substituted Hantzsch ester as a mi...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/anie.202107253

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Name:
Engineering & Physical Sciences Research Council
Grant:
EP/J013501/1
Publisher:
Wiley
Journal:
Angewandte Chemie International Edition More from this journal
Volume:
60
Issue:
45
Pages:
24116-24123
Publication date:
2021-08-27
Acceptance date:
2021-08-25
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Pmid:
34449968
Language:
English
Keywords:
Pubs id:
1193358
Local pid:
pubs:1193358
Deposit date:
2021-10-21

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