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A molecular-beam optical Stark study of lines in the (1,0) band of the F4Δ7/2-X4Δ7/2 transition of iron monohydride, FeH

Abstract:

A supersonic molecular beam of iron monohydride, FeH, has been generated using a laser ablation/chemical reaction scheme and probed at near-natural linewidth resolution by optical Stark spectroscopy utilizing laser-induced fluorescence detection. The observed Stark splitting in Q(3.5) and R(3.5) lines of the F4Δ7/2← X4Δ7/2 (1,0) transition were analyzed to determine values for the magnitudes of the permanent electric dipole moments, |μ|, which were found to be 2.63(3) and 1.29(3) D for the X4...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1063/1.2194551

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Institution:
Arizona State University, Arizona, USA
Department:
Department of Chemistry and Biochemistry
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Institution:
Arizona State University, Arizona, USA
Department:
Department of Chemistry and Biochemistry
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Institution:
University of Oxford
Research group:
Professor John Brown's Research Group
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Physical and Theoretical Chemistry Laboratory
More by this author
Institution:
University of Oxford
Research group:
Professor John Brown's Research Group
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Physical and Theoretical Chemistry Laboratory
Publisher:
American Institute of Physics Publisher's website
Journal:
The Journal of Chemical Physics Journal website
Volume:
124
Issue:
18
Pages:
Article: 184307
Publication date:
2006-05-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:67f78048-83e6-4348-8a5f-d864a82e5928
Local pid:
ora:1740

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