Journal article
Enantio- and diastereoselective palladium catalysed arylative and vinylative allene carbocyclisation cascades.
- Abstract:
- The enantioselective synthesis of heavily decorated spirolactams has been accomplished via an arylative or vinylative allene carbocyclisation cascade. Mediated by silver phosphate, a range of allene-linked pro-nucleophiles and aryl or vinyl iodides were reacted in the presence of catalytic Pd(OAc)2 and chiral bis(oxazoline) ligands to afford the spirolactam products in good yields and high enantio- and diastereoselectivities.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/c3cc42079e
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Authors
Bibliographic Details
- Journal:
- Chemical Communications
- Volume:
- 49
- Issue:
- 46
- Pages:
- 5265-5267
- Publication date:
- 2013-06-01
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- Source identifiers:
-
401533
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:401533
- UUID:
-
uuid:67e634b0-881d-43cd-aa0a-dd9da8d3cc54
- Local pid:
- pubs:401533
- Deposit date:
- 2013-11-17
Terms of use
- Copyright date:
- 2013
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