- Abstract:
-
The mechanistic and regiochemical aspects in the Au(I)-catalyzed intermolecular hydroalkoxylation of allenes have been studied computationally. The most favorable pathway is nucleophilic attack of an Au(I)-coordinated allene, which occurs irreversibly. An Au(I)-catalyzed mechanism is proposed that allows the facile interconversion of regioisomeric allylic ether products. The regioisomers are connected via a stabilized diether intermediate with a C-Au sigma-bond, which successfully explains th...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ol9004646
-
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- Journal:
- Organic letters
- Volume:
- 11
- Issue:
- 11
- Pages:
- 2237-2240
- Publication date:
- 2009-06-05
- DOI:
- EISSN:
-
1523-7052
- ISSN:
-
1523-7060
- URN:
-
uuid:67d2dc99-ab83-4e93-8c1f-e8c7bc0a62cb
- Source identifiers:
-
117480
- Local pid:
- pubs:117480
- Language:
- English
- Copyright date:
- 2009
Journal article
Gold(I)-catalyzed intermolecular hydroalkoxylation of allenes: a DFT study.
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