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Gold(I)-catalyzed intermolecular hydroalkoxylation of allenes: a DFT study.

Abstract:
The mechanistic and regiochemical aspects in the Au(I)-catalyzed intermolecular hydroalkoxylation of allenes have been studied computationally. The most favorable pathway is nucleophilic attack of an Au(I)-coordinated allene, which occurs irrevers...Expand abstract...
Publication status:
Published

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Publisher copy:
10.1021/ol9004646

Authors


Maseras, F More by this author
Journal:
Organic letters More in this journal
Volume:
11
Issue:
11
Pages:
2237-2240
Publication date:
2009-06-19
DOI:
EISSN:
1523-7052
ISSN:
1523-7060
URN:
uuid:67d2dc99-ab83-4e93-8c1f-e8c7bc0a62cb
Source identifiers:
117480
Local pid:
pubs:117480
Language:
English

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