Journal article
The 193nm photolysis of NO2: NO(v) vibrational distribution, O(D-1) quantum yield and emission from vibrationally excited NO2
- Abstract:
-
Time resolved Fourier transform infrared emission has been used to study the photolysis of NO2 and its dimer N2O4 at 193 nm. NO(ν) populations from the photolysis of NO2 show a bimodal distribution, peaking at ν = 5 and with a subsidiary maximum at ν = 14, close to the energetically allowed limit. The results are discussed in terms of previous measurements near this photolysis wavelength of the kinetic energies of the two possible O atomic fragments, O(3P) and O(1D), and on the electronic sta...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- MOLECULAR PHYSICS
- Volume:
- 103
- Issue:
- 13
- Pages:
- 1727-1733
- Publication date:
- 2005-07-10
- DOI:
- EISSN:
-
1362-3028
- ISSN:
-
0026-8976
Item Description
- Language:
- English
- Pubs id:
-
pubs:39554
- UUID:
-
uuid:679eb282-3f98-4377-ad37-57fec1305970
- Local pid:
- pubs:39554
- Source identifiers:
-
39554
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2005
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