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Organozirconocene nucleophiles in Cu-catalysed asymmetric transformations: methodologies, applications to total synthesis and NMR mechanistic studies

Abstract:

The development of powerful and adaptable methods to form new C-C bond enantioselectively is highly desirable. Many methodologies emerged in recent years using a wide array of nucleophilic organometallics and catalytic metals1,2. In this work, a general introduction on the current development of Cu-catalysed asymmetric additions is primarily described (Chapter 1). We particularly focus on the applications of such methodologies, the study of their mechanisms and the transition from using commo...

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Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author

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Role:
Supervisor
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Language:
English
Keywords:
UUID:
uuid:671c98a0-185b-41af-abac-174617879ab4
Deposit date:
2016-12-02

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