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Effects of Coadsorbed Oxygen on the Infrared Driven Decomposition of N2O on Isolated Rh-5(+) Clusters

Abstract:

The thermally induced decomposition of nitrous oxide on isolated Rh 5+ and Rh 5O + clusters has been investigated using mid-infrared multiple photon dissociation spectroscopy. The presence of a single coadsorbed oxygen atom is observed to have a profound effect on the cluster surface processes that ensue following infrared heating of the cluster. Exciting the infrared active N 2O bending transition in Rh 5N 2O + results predominantly (≥85%) in molecular desorption of the N 2O moiety, while th...

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Publication status:
Published

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Publisher copy:
10.1021/jz2012963

Authors


Hermes, AC More by this author
Hamilton, SM More by this author
Hopkins, WS More by this author
Harding, DJ More by this author
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Journal:
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume:
2
Issue:
24
Pages:
3053-3057
Publication date:
2011-12-15
DOI:
EISSN:
1948-7185
ISSN:
1948-7185
URN:
uuid:66c2d236-c561-48aa-8601-d67e4468de69
Source identifiers:
239921
Local pid:
pubs:239921

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