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Observation and reactivity of the chainlike species ([Al(PO4)(2)](3-))(n) during the X-ray diffraction investigation of the hydrothermal synthesis of the super-sodalite sodium aluminophosphate MIL-74 (Na2Al7(PO4)(12)center dot 4trenH(3)center dot Na(H2O)(16))

Abstract:

The hydrothermal synthesis of the aluminum phosphate Na2Al 7(PO4)12•4trenH3•Na(H 2O)16 (MIL-74) has been studied by X-ray diffraction (conventional source) and in-situ time-resolved energy-dispersive X-ray diffraction (synchrotron radiation). Before the crystallization of MIL-74, the reaction of the starting aqueous aluminophosphate gel containing the tren species (tris(2-aminoethyl)amine) and sodium hydroxide gives rise to the formation of a hydrated chainlike solid Al(PO4)2• trenH3•6H2O (ph...

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Publication status:
Published

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Publisher copy:
10.1021/jp0485901

Authors


Loiseau, T More by this author
Beitone, L More by this author
Millange, F More by this author
Taulelle, F More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Journal:
JOURNAL OF PHYSICAL CHEMISTRY B
Volume:
108
Issue:
52
Pages:
20020-20029
Publication date:
2004-12-30
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:66068df5-e806-484a-a710-e4e58b926cfc
Source identifiers:
51168
Local pid:
pubs:51168
Language:
English

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