Journal article
Silicon tethered alkenyl transfer and Type I ene reactions
- Abstract:
-
A range of vinyl silanes was prepared in order to investigate the possibility of effecting silicon tethered Type I ene cyclisations analogous to our previously reported Type II variant. Some of these substrates were found to undergo overall stereospecific alkenyl transfer via silacyclopentanol intermediates; in a homologous series, alkenyl transfer was accompanied by dehydration to provide 7-silylhepta-2,4-dienes in moderate yield. Formal Type I ene cyclisations were found to be successful fo...
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- Publication status:
- Published
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- Publisher copy:
- 10.1016/S0040-4020(00)00738-9
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Authors
Bibliographic Details
- Journal:
- TETRAHEDRON
- Volume:
- 56
- Issue:
- 42
- Pages:
- 8321-8333
- Publication date:
- 2000-10-13
- DOI:
- ISSN:
-
0040-4020
- Source identifiers:
-
55239
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:55239
- UUID:
-
uuid:65a35940-c5bf-480e-877e-a169aa14c053
- Local pid:
- pubs:55239
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2000
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