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Silicon tethered alkenyl transfer and Type I ene reactions

Abstract:

A range of vinyl silanes was prepared in order to investigate the possibility of effecting silicon tethered Type I ene cyclisations analogous to our previously reported Type II variant. Some of these substrates were found to undergo overall stereospecific alkenyl transfer via silacyclopentanol intermediates; in a homologous series, alkenyl transfer was accompanied by dehydration to provide 7-silylhepta-2,4-dienes in moderate yield. Formal Type I ene cyclisations were found to be successful fo...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Journal:
TETRAHEDRON
Volume:
56
Issue:
42
Pages:
8321-8333
Publication date:
2000-10-13
DOI:
ISSN:
0040-4020
URN:
uuid:65a35940-c5bf-480e-877e-a169aa14c053
Source identifiers:
55239
Local pid:
pubs:55239

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