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Aspects of organosulphur chemistry

Abstract:

Section I of this thesis is concerned with the rearrangement of allylic sulphinate esters to sulphones. Isomerisation of cyclohex-2-enyl toluene-p-sulphinate (1) and several related substituted sulphinates was investigated particularly in ionising solvents such as formamide. The substituted systems, 1-[2H]-cyclohex-2-enyl toluene-p- sulphinate and 3-methylcyclohex-2-enyl toluene-p-sulphinate (2), gave sulphones with the label scrambled between C-1 and C-3. Rearrangement of the ...

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Institution:
University of Oxford
Division:
MPLS
Role:
Author

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Role:
Supervisor
Role:
Supervisor
Publication date:
1983
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Language:
English
Subjects:
UUID:
uuid:64f41404-519b-4cd8-9426-1f3a8ebe717c
Local pid:
td:603839504
Source identifiers:
603839504
Deposit date:
2015-02-04

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