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A short synthesis of aphanamol I in both racemic and enantiopure forms

Abstract:
A short synthesis of the biologically active sesquiterpene natural product (+)-aphanamol I in both racemic and enantiopure forms is reported. Key steps include: a catalytic enantioselective conjugate addition, an oxidative radical cyclisation, and a ringexpanding Claisen rearrangement.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1002/chem.201602669

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
John Fell Fund More from this funder
Publisher:
Wiley Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
22
Issue:
33
Pages:
11597–11600
Publication date:
2016-07-08
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
URN:
uuid:64e7fa3b-18f7-453c-b44e-54a76b3f1439
Source identifiers:
626955
Local pid:
pubs:626955
Paper number:
33

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