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A high resolution spectroscopic study of the open-shell complex ArNO2

Abstract:

Microwave and infrared spectra of the open-shell complex ArNO2 have been recorded. The microwave spectrum (6-18 GHz) consisted solely of the a-type transitions 505→,404→303, 303→202, and 202→101 involving the Ka=0 state and 523→422, 524→423, 422→321, 423→322, 321→220, 322→221 involving the Ka = 2 state. These transitions showed structure due to fine, magnetic hyperfine and electric quadrupole interactions. The infrared spectrum, associated with the ν3 asymmetric vibrational mode of the NO2 mo...

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Publication status:
Published

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Publisher copy:
10.1063/1.472998

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
105
Issue:
16
Pages:
6756-6770
Publication date:
1996-10-22
DOI:
ISSN:
0021-9606
URN:
uuid:648e6501-19cf-4759-b1e9-6455f02851b4
Source identifiers:
45274
Local pid:
pubs:45274
Language:
English

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