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New group 4 organometallic and imido compounds of diamide-diamine and related dianionic O2N2-donor ligands

Abstract:

New group 4 compounds supported by the tetradentate diamide-diamine ligand N2NN′ are reported (N2NN′ = (2-C 5H4N)CH2N(CH2CH 2NSiMe3)2) along with some comparative studies with the new bis(alkoxide)-diamine ligand O2NN′ (O 2NN′ = (2-C5H4N)CH2N(CH 2-CMe2O)2). Reaction of the previously described ZrCl2(N2NN′) (1) with 2 equiv of MeLi or PhCH2MgCl gave ZrR2(N2NN′) (R = Me (2) or CH2Ph (3)). Reaction of 1 with 1 equiv of RCH2MgCl gave the monoalkyl analogues ZrCl(R)(N2NN′) (R = CH2Ph (6) or CH2SiM...

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Publication status:
Published

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Publisher copy:
10.1021/om0506365

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS
Volume:
24
Issue:
23
Pages:
5586-5603
Publication date:
2005-11-07
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:645d55a6-28b6-4f4f-9b5e-7d2ce894e378
Source identifiers:
51311
Local pid:
pubs:51311

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