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Branched tetrahydrofuran alpha,alpha-disubstituted-delta-sugar amino acid scaffolds from branched sugar lactones: a new family of foldamers?

Abstract:
Efficient SN2 ring closure of open chain trihydroxytriflates-in which the leaving group is on a primary carbon adjacent to a quaternary centre-provides access to tetrahydrofurans with branched carbon chains from branched carbohydrate lactones; the first examples of a new class of branched chain tetrahydrofuran α,α-disubstituted-δ-sugar amino acid scaffolds are described. © 2005 Elsevier Ltd. All rights reserved.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
TETRAHEDRON LETTERS
Volume:
46
Issue:
34
Pages:
5761-5765
Publication date:
2005-08-22
DOI:
ISSN:
0040-4039
Source identifiers:
39582
Language:
English
Pubs id:
pubs:39582
UUID:
uuid:644ecf70-caa7-407f-a95c-441357ddae6c
Local pid:
pubs:39582
Deposit date:
2012-12-19

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