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Branched tetrahydrofuran alpha,alpha-disubstituted-delta-sugar amino acid scaffolds from branched sugar lactones: a new family of foldamers?

Abstract:
Efficient SN2 ring closure of open chain trihydroxytriflates-in which the leaving group is on a primary carbon adjacent to a quaternary centre-provides access to tetrahydrofurans with branched carbon chains from branched carbohydrate lactones; the first examples of a new class of branched chain tetrahydrofuran α,α-disubstituted-δ-sugar amino acid scaffolds are described. © 2005 Elsevier Ltd. All rights reserved.
Publication status:
Published

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Authors


Simone, MI More by this author
Soengas, R More by this author
Newton, CR More by this author
Watkin, DJ More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Journal:
TETRAHEDRON LETTERS
Volume:
46
Issue:
34
Pages:
5761-5765
Publication date:
2005-08-22
DOI:
ISSN:
0040-4039
URN:
uuid:644ecf70-caa7-407f-a95c-441357ddae6c
Source identifiers:
39582
Local pid:
pubs:39582
Language:
English

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