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Homogeneous catalysis of electrochemical reactions. Channel electrode voltammetry and the EC′ mechanism

Abstract:
The shape of the current-voltage curves at a channel electrode have been calculated for the various situations of the catalytic (EC’) mechanism. In particular the halfwave potential and limiting current are found to be highly sensitive to the solution-flow rate and to the concentrations of the mediator and substrate employed. These observations provide a ready method of unambiguously characterizing the different pathways.
Publication status:
Published

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Publisher copy:
10.1002/elan.1140040207

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Institution:
University of Oxford
Role:
Author
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Institution:
University of Oxford
Role:
Author
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Institution:
University of Oxford
Role:
Author
Journal:
Electroanalysis
Volume:
4
Issue:
2
Pages:
167-182
Publication date:
1992-02-01
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
Source identifiers:
43800
Keywords:
UUID:
uuid:63fce6b9-a1b4-4fd8-b1d0-8bb2e8787ed2
Local pid:
pubs:43800
Deposit date:
2012-12-19

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