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The effect of 4 '-substituents on the kinetics of ligand substitution in 2,2 ': 6 ',2 ''-terpyridine platinum(II) complexes

Abstract:
The rates of hydrolysis of five (4′-substituted-2,2′:6′,2′-terpyridine) platinum(II) (n-propylamine) complexes exhibit a high sensitivity to the electronic properties of the terpyridine ligand; analysis using the Hammett relationship gives a ρ value of +2.34.
Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MSD, Physiology Anatomy and Genetics
Role:
Author
Journal:
JOURNAL OF CHEMICAL RESEARCH-S
Issue:
12
Pages:
566-568
Publication date:
2000-12-05
ISSN:
0308-2342
URN:
uuid:63ce3ffa-51c2-47a2-93d4-f1ac9e5c14ef
Source identifiers:
274979
Local pid:
pubs:274979
Language:
English

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