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Microwave-enhanced electroanalytical processes: generator-collector voltammetry at paired gold electrode junctions.

Abstract:

Generator-collector electrode systems allow redox processes and reaction intermediates from multi-step electrode reactions to be monitored. Analytically, collector electrode current responses are insightful and highly sensitive due to (i) the absence of capacitive current components and (ii) an enhanced current response due to 'feedback' between generator and collector electrode. Here, a symmetric gold-gold junction grown by controlled electro-deposition is employed for generator-collector vo...

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Publication status:
Published

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Publisher copy:
10.1039/b900292h

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
The Analyst
Volume:
134
Issue:
5
Pages:
887-892
Publication date:
2009-05-05
DOI:
EISSN:
1364-5528
ISSN:
0003-2654
URN:
uuid:630bd065-16d5-4f85-b1e6-2d8ec7caa547
Source identifiers:
41147
Local pid:
pubs:41147
Language:
English

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