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Photochemical stability of N@C60 and its pyrrolidine derivatives

Abstract:: Pyrrolidine derivatives of N@C60 have been synthesized and characterized. The photochemical stability of the derivatives as well as pristine N@C60 are studied and compared. While the attachment of a pyrrolidine group to C60 cage significantly lowers the photolytic stability of N@C60, the effect of a peripheral optically active pyrenyl group on photoinduced decay is negligible. A mechanism involving carbon-carbon bond dissociation and a subsequent inversion of the endohedral nitrogen atom is p...
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APA Style

Liu, G., Khlobystov, A., Ardavan, A., Briggs, G., & Porfyrakis, K. (2011). Photochemical stability of N@C60 and its pyrrolidine derivatives. Chemical Physics Letters, 508(4-6), 187–190.

MLA Style

Liu, G., et al. “Photochemical Stability of N@C60 and Its Pyrrolidine Derivatives.” Chemical Physics Letters, vol. 508, no. 4-6, 2011, pp. 187–90.

Chicago Style

Liu, G, A Khlobystov, A Ardavan, G Briggs, and K Porfyrakis. 2011. “Photochemical Stability of N@C60 and Its Pyrrolidine Derivatives.” Chemical Physics Letters 508 (4-6): 187–90.
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Publisher copy:: 10.1016/j.cplett.2011.04.039

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+ Liu, G More by this author

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+ Khlobystov, A More by this author

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+ Ardavan, A More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Physics

Sub department:

Condensed Matter Physics

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+ Briggs, G More by this author

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Author

+ Porfyrakis, K More by this author

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Author

Bibliographic Details

Journal:: Chemical Physics Letters
Volume:: 508
Issue:: 4-6
Pages:: 187-190
Publication date:: 2011-05-27
DOI:: 10.1016/j.cplett.2011.04.039
ISSN:: 0009-2614

Item Description

Language:: English
Pubs id:: pubs:179162
UUID:: uuid:62b9f612-7437-4a72-a9b9-61a183eb6b78
Local pid:: pubs:179162
Source identifiers:: 179162
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2011

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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