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Exploring template-bound dinuclear copper porphyrin nanorings by EPR spectroscopy

Abstract:

Electron paramagnetic resonance (EPR) spectroscopy has been used to study the molecular geometry as well as metal-ligand interactions in ten-membered porphyrin nanorings (c-P10Cu2) containing two copper and eight zinc centers. The presence of copper in the structures allows intramolecular interactions, including dipolar interactions between electron spins and hyperfine interactions to be quantified. Results obtained for c-P10Cu2 samples bound to two molecular templates with four or five bindi...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1039/C6SC01810F

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Department:
Oxford, MPLS, Chemistry, Centre for Advanced Electron Spin Resonance
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Department:
Oxford, MPLS, Chemistry Research Laboratory
More by this author
Department:
Oxford, MPLS, Chemistry Research Laboratory
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Science Journal website
Publication date:
2016
DOI:
EISSN:
2041-6539
ISSN:
2041-6520
Pubs id:
pubs:636276
URN:
uri:629dc337-9c94-4ea9-b3f8-a6082bc93238
UUID:
629dc337-9c94-4ea9-b3f8-a6082bc93238
Local pid:
pubs:636276

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