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A family of 13 tetranuclear zinc(II)-lanthanide(III) complexes of a [3+3] Schiff-base macrocycle derived from 1,4-diformyl-2,3-dihydroxybenzene.

Abstract:

A family of thirteen tetranuclear heterometallic zinc(II)-lanthanide(III) complexes of the hexa-imine macrocycle (L(Pr))(6-), with general formula Zn(II)(3)Ln(III)(L(Pr))(NO(3))(3)·xsolvents (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm or Yb), were prepared in a one-pot synthesis using a 3:1:3:3 reaction of zinc(II) acetate, the appropriate lanthanide(III) nitrate, the dialdehyde 1,4-diformyl-2,3-dihydroxybenzene (H(2)L(1)) and 1,3-diaminopropane. A hexanuclear homometallic zinc(II) m...

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Publication status:
Published

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Publisher copy:
10.1039/c1dt11038a

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Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
40
Issue:
43
Pages:
11425-11432
Publication date:
2011-11-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:62768879-aa9c-4d3d-846d-7d23a5c190c1
Source identifiers:
206112
Local pid:
pubs:206112
Language:
English

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