The preparation of a series of amidinato and guanidinato zinc halide complexes incorporating ligands of varying steric bulk is described, and their thermal stabilities compared. Salt elimination reactions between [M(Giso)] (M = K or Li; Giso = [(ArN)(2)CNCy(2)](-), Ar = 2,6-diisopropylphenyl, Cy = cyclohexyl) and ZnX(2) (X = I or Br) have yielded the monomeric complexes [(Giso)ZnI] and [(Giso)Zn(mu-Br)(2)Li(OEt(2))(2)]. Both have been crystallographically characterised and the former shown to...Expand abstract
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Bulky guanidinato and amidinato zinc complexes and their comparative stabilities.
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