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Bulky guanidinato and amidinato zinc complexes and their comparative stabilities.

Abstract:

The preparation of a series of amidinato and guanidinato zinc halide complexes incorporating ligands of varying steric bulk is described, and their thermal stabilities compared. Salt elimination reactions between [M(Giso)] (M = K or Li; Giso = [(ArN)(2)CNCy(2)](-), Ar = 2,6-diisopropylphenyl, Cy = cyclohexyl) and ZnX(2) (X = I or Br) have yielded the monomeric complexes [(Giso)ZnI] and [(Giso)Zn(mu-Br)(2)Li(OEt(2))(2)]. Both have been crystallographically characterised and the former shown to...

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Publication status:
Published

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Publisher copy:
10.1039/c0dt00589d

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
39
Issue:
37
Pages:
8788-8795
Publication date:
2010-10-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:6268887e-ccf4-4198-b8a7-d480e13254e7
Source identifiers:
83859
Local pid:
pubs:83859
Language:
English

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