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STUDIES ON THE MECHANISM OF DEACETOXY DEACETYLCEPHALOSPORIN-C SYNTHASE USING CYCLOPROPYL SUBSTITUTED CEPHALOSPORIN PROBES

Abstract:
Cyclopropyl substituted cephalosporin analogues were prepared and evaluated as substrates for the Fe II/α-ketoglutarate dependent oxygenase, DAOC-DAC synthase; the first example of catalytic product formation from a Cyclopropyl ring cleavage pathway by an α-ketoglutarate dependent oxygenase is reported.
Publication status:
Published

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Publisher copy:
10.1039/c39910000768

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
Issue:
11
Pages:
768-770
Publication date:
1991-06-01
DOI:
ISSN:
0022-4936
URN:
uuid:6223aea7-a9a1-4a53-abd3-32cab69ae44b
Source identifiers:
43597
Local pid:
pubs:43597

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