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A novel approach for the quantitative kinetic study of reactions at solid/liquid interfaces in the presence of power ultrasound.

Abstract:

A novel cell and procedure is described which permits the quantitative mechanistic study of ultrasonically enhanced reactions which occur at solid/liquid interfaces. A model of a controlled and calculable time-average rate of mass transport to and from the interface is used in order to compare experimental results with theoretical predictions based on mechanistic reaction schemes. In this way concentrations of mechanistically significant species near the interface can be related to those in b...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Rebbitt, TO More by this author
Journal:
Ultrasonics sonochemistry
Volume:
4
Issue:
1
Pages:
1-7
Publication date:
1997-01-05
DOI:
EISSN:
1873-2828
ISSN:
1350-4177
URN:
uuid:6221d456-3f36-42e8-9784-dd14fc362cd9
Source identifiers:
31832
Local pid:
pubs:31832
Language:
English
Keywords:

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