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Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media.

Abstract:
The electrode potentials of quinone redox centres in aqueous solutions can be tuned by varying the electrolyte cation identity. The phenomenon is due to the ion pairing effect of the tetra-n-butylammonium cation with the semiquinone intermediate species.
Publication status:
Published

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Publisher copy:
10.1039/c1cc14191k

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Chemical Communications More from this journal
Volume:
47
Issue:
41
Pages:
11426-11428
Publication date:
2011-11-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Language:
English
UUID:
uuid:6216e81e-7cfc-4beb-a6b4-162d5b9ebd21
Local pid:
pubs:180562
Source identifiers:
180562
Deposit date:
2012-12-19

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