- Abstract:
-
Valence photoelectron (PE) spectra have been measured for ReO(3)Me using a synchrotron source for photon energies ranging between 20 and 110 eV. Derived branching ratios (BR) and relative partial photoionization cross sections (RPPICS) are interpreted in the context of a bonding model calculated using density functional theory (DFT). Agreement between calculated and observed ionization energies (IE) is excellent. The 5d character of the orbitals correlates with the 5p --> 5d resonances of ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic020547+
-
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- Journal:
- Inorganic chemistry
- Volume:
- 42
- Issue:
- 6
- Pages:
- 1908-1918
- Publication date:
- 2003-03-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:620cdb01-1a72-4b9d-89c2-b4d2ed8249de
- Source identifiers:
-
38559
- Local pid:
- pubs:38559
- Language:
- English
- Copyright date:
- 2003
Journal article
Electronic structure of ReO3Me by variable photon energy photoelectron spectroscopy, absorption spectroscopy and density functional calculations.
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