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N-H cleavage vs. Werner complex formation: reactivity of cationic group 14 tetrelenes towards amines

Abstract:

β-Diketiminate ligands featuring backbone NMe2 groups have been exploited to access a series of two-coordinate cations of the type [(N-nacnac)E]+ (E = Si, Ge, Sn), whose reactivity towards N-H bonds has been investigated. While the heavier group 14 systems react via simple adduct formation, N-H oxidative addition occurs for E = Si consistent with differences in EII/EIV redox potentials. The structurally characterized Ge/Sn adducts can be viewed as models for the corresponding (transient) Si s...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/d0cc00875c

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0001-5882-8896
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0001-9450-2594
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0003-4202-6869
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications More from this journal
Volume:
56
Issue:
2020
Pages:
4684-4687
Publication date:
2020-03-16
Acceptance date:
2020-03-16
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pmid:
32211709
Language:
English
Keywords:
Pubs id:
1098854
Local pid:
pubs:1098854
Deposit date:
2020-04-18

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