- We report a versatile infrared spectroscopic method for studying redox chemistry of metalloproteins, and demonstrate for the first time electrochemically-induced changes to the active site of the regulatory [NiFe]-hydrogenase from Ralstonia eutropha. A carbon particle network working electrode allows control over a wide potential window without the need for solution mediators.
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- Peer reviewed
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- Physical Chemistry Chemical Physics Journal website
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- Healy et al.
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- Authors will always retain their copyright for articles published with the Royal Society of Chemistry. This is the accepted manuscript version of the article. The final version is available online from the Royal Society of Chemistry at: [10.1039/C3CP00119A].
Attenuated total reflectance infrared spectroelectrochemistry at a carbon particle electrode; unmediated redox control of a [NiFe]-hydrogenase solution.
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