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Attenuated total reflectance infrared spectroelectrochemistry at a carbon particle electrode; unmediated redox control of a [NiFe]-hydrogenase solution.

Abstract:
We report a versatile infrared spectroscopic method for studying redox chemistry of metalloproteins, and demonstrate for the first time electrochemically-induced changes to the active site of the regulatory [NiFe]-hydrogenase from Ralstonia eutropha. A carbon particle network working electrode allows control over a wide potential window without the need for solution mediators.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c3cp00119a

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Funding agency for:
Healy, A
More from this funder
Funding agency for:
Ash, P
Grant:
Starting Grant 258600
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Funding agency for:
Vincent, K
Grant:
Starting Grant 258600
More from this funder
Funding agency for:
Vincent, K
Grant:
Starting Grant 258600
More from this funder
Funding agency for:
Vincent, K
Grant:
Starting Grant 258600
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Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Physical Chemistry Chemical Physics Journal website
Volume:
15
Issue:
19
Pages:
7055-7059
Publication date:
2016-03-22
Acceptance date:
2016-03-22
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Source identifiers:
394913
Language:
English
Pubs id:
pubs:394913
UUID:
uuid:6187f5db-4b29-4ecf-947c-32ba5b377c02
Local pid:
pubs:394913
Deposit date:
2013-11-16

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