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Nonlinear relaxation in redox processes in ionic and polar liquids

Abstract:

Simulations have been performed to investigate the relaxation dynamics of the solvent around probe ions in the ionic liquid dimethylimidazolium hexafluorophosphate and in the polar liquid acetonitrile. The time scale of the relaxation dynamics is found to be different in the two cases, although our earlier work showed that the Marcus free energy curves, solvent rearrangement energies, and redox activation free energies were very similar. We also observe differences between the nonequilibrium ...

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Publication status:
Published

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Publisher copy:
10.1021/jp804958p

Authors


Streeter, I More by this author
Lynden-Bell, RM More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
112
Issue:
37
Pages:
14538-14544
Publication date:
2008-09-18
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:60f26d15-00e9-4275-b8af-13c1a4f63e52
Source identifiers:
40850
Local pid:
pubs:40850
Language:
English

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