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Fluorescent copper(II) bis(thiosemicarbazonates): synthesis, structures, electron paramagnetic resonance, radiolabeling, in vitro cytotoxicity and confocal fluorescence microscopy studies.

Abstract:

Copper bis(4-ethyl-3-thiosemicarbazonato) acenaphthenequinone (1) and copper bis(4-methyl-3-thiosemicarbazonato) acenaphthenequinone (2) are synthesized and characterized in solution, in the solid state, and radiolabeled. Serum-protein binding radioassays show good stability in solution and about 25 % binding to protein over 1 h, which is comparable with the hypoxia selective tracer [(64)Cu(ATSM)]. Cyclic voltammetry shows fast and reversible reduction at redox potentials similar to the value...

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Publication status:
Published

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Publisher copy:
10.1002/asia.200900446

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Journal:
Chemistry, an Asian journal
Volume:
5
Issue:
3
Pages:
506-519
Publication date:
2010-03-05
DOI:
EISSN:
1861-471X
ISSN:
1861-4728
URN:
uuid:60beba3c-9217-4339-9f6e-7c89b2cd1fb9
Source identifiers:
51995
Local pid:
pubs:51995

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