- Abstract:
-
Deltahedral nine-atom clusters of silicon, Si(9)(2-), were synthesized by mild oxidation of a liquid ammonia solution of K(12)Si(17) with Ph(3)GeCl in the presence of 18-crown-6 (1,4,7,10,13,16-hexaoxacyclooctadecane) or 2,2,2-crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane). The clusters were structurally characterized in [K(18-crown-6)](2)Si(9).C(5)H(5)N (yellow; orthorhombic, Pnma; a = 14.013(1), b = 18.108 (1), c = 18.320 (1) A; Z = 4) crystallized from a pyridine soluti...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic0500964
-
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- Journal:
- Inorganic chemistry
- Volume:
- 44
- Issue:
- 8
- Pages:
- 2654-2658
- Publication date:
- 2005-04-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:6059ea54-e60b-47ab-bc4a-d847097efc14
- Source identifiers:
-
33052
- Local pid:
- pubs:33052
- Language:
- English
- Copyright date:
- 2005
Journal article
Ligand-free deltahedral clusters of silicon in solution: synthesis, structure, and electrochemistry of Si9(2-).
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