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Organolithium-induced enantioselective alkylative double ring-opening of epoxides: synthesis of enantioenriched unsaturated amino alcohols

Abstract:
The use of (-)-sparteine as an external chiral ligand in enantioselective organolithium-induced alkylative double ring-opening of dihydropyrrole epoxides and 7-azanorbornene-type epoxides gives unsaturated acyclic amino alcohols, and amino cyclohexenols in up to 87% ee. © 2004 Elsevier Ltd. All rights reserved.
Publication status:
Published

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Publisher copy:
10.1016/j.tet.2004.02.055

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Maxwell, CR More by this author
Matthews, IR More by this author
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Journal:
TETRAHEDRON
Volume:
60
Issue:
16
Pages:
3611-3624
Publication date:
2004-04-12
DOI:
ISSN:
0040-4020
URN:
uuid:6059beb0-1b0b-41ee-8503-4e34ab193823
Source identifiers:
39020
Local pid:
pubs:39020

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