Journal article

Synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared

Abstract:: Quinoidalization results in amazingly intense near-IR absorption in 1 (λ(max) = 1080 nm), whereas the shorter dimer 2 (λ(max) = 780 nm) is less conjugated because steric interactions force it into a contorted geometry. The crystal structure of 1 shows that the 62-atom chromophore is bow-shaped in the solid state.

Publication status:: Published

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APA Style

Blake, I., Rees, L., Claridge, T., & Anderson, H. (2000). Synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 39(10), 1818-+.

MLA Style

Blake, I., et al. “Synthesis and Crystal Structure of a Cumulenic Quinoidal Porphyrin Dimer with Strong Electronic Absorption in the Infrared.” ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, vol. 39, no. 10, 2000, pp. 1818-+.

Chicago Style

Blake, I, L Rees, T Claridge, and H Anderson. 2000. “Synthesis and Crystal Structure of a Cumulenic Quinoidal Porphyrin Dimer with Strong Electronic Absorption in the Infrared.” ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 39 (10): 1818-+.
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Publisher copy:: 10.1002/(SICI)1521-3773(20000515)39:10<1818::AID-ANIE1818>3.0.CO;2-E

Authors

+ Blake, I More by this author

Role:: Author

+ Rees, L More by this author

Role:: Author

+ Claridge, T More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Anderson, H More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

Journal:: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION More from this journal
Volume:: 39
Issue:: 10
Pages:: 1818-+
Publication date:: 2000-01-01
DOI:: 10.1002/(SICI)1521-3773(20000515)39:10<1818::AID-ANIE1818>3.0.CO;2-E
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: conjugation

porphyrinoids

quinodimethanes

oligomers

chromophores
Pubs id:: pubs:51837
UUID:: uuid:602638c0-02d8-4cfd-8bbd-6ef2da3ba070
Local pid:: pubs:51837
Source identifiers:: 51837
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2000

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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