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The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)

Abstract:
The 248 nm photolysis of NO2 results in an inverted vibrational distribution in NO(v) which agrees well with previous REMPI measurements. It was shown that the quenching of the higher levels in collisions with NO2 have clear importance of resonance energy transfer to the NO2(0,0,1) level. Emission from NO2 was found, produced from the photolysis of N2O4, and its spectral signature was similar to that resulting from electronic excitation of NO2.
Publication status:
Published

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Publisher copy:
10.1063/1.1521724

Authors


Morrell, C More by this author
Breheny, C More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
117
Issue:
24
Pages:
11121-11130
Publication date:
2002-12-22
DOI:
ISSN:
0021-9606
URN:
uuid:5ff3ad70-7993-47e2-a617-d4e2ef09251a
Source identifiers:
38471
Local pid:
pubs:38471
Language:
English

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