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Selective ion-exchange intercalation of isomeric dicarboxylate anions into the layered double hydroxide [LiAl2(OH)(6)]Cl center dot H2O

Abstract:
The dicarboxylate anions 1,4-benzenedicarboxylate and fumarate can be selectively intercalated into the layered double hydroxide [LiAl2(OH)6]Cl·H2O from equimolar molar mixtures of the 1,2-, 1,3-, and 1,4-benzenedicarboxylate and fumarate and maleate isomers, respectively. Time-resolved in situ energy-dispersive X-ray diffraction studies have shown that these are the thermodynamic products following the conversion of an initial phase in which all the anions are simultaneously intercalated.
Publication status:
Published

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Publisher copy:
10.1021/cm9705202

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
CHEMISTRY OF MATERIALS More from this journal
Volume:
10
Issue:
1
Pages:
351-355
Publication date:
1998-01-01
DOI:
EISSN:
1520-5002
ISSN:
0897-4756


Language:
English
Pubs id:
pubs:51155
UUID:
uuid:5fc199e2-433b-466c-aaaf-1173e64964cf
Local pid:
pubs:51155
Source identifiers:
51155
Deposit date:
2012-12-19

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