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A velocity map imaging study of gold-rare gas complexes: Au-Ar, Au-Kr, and Au-Xe.

Abstract:

The ultraviolet photodissociation dynamics of the gold-rare gas atom van der Waals complexes (Au-RG, RG = Ar, Kr, and Xe) have been studied by velocity map imaging. Photofragmentation of Au-Ar and Au-Kr at several wavelengths permits extrapolation to zero of the total kinetic energy release (TKER) spectra as monitored in the Au((2)P(3/2)(o)[5d(10)6p]) fragment channel, facilitating the determination of ground state dissociation energies of D(0)(")(Au-Ar) = 149+/-13 cm(-1) and D(0)(")(Au-Kr) =...

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Publication status:
Published

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Publisher copy:
10.1063/1.3432127

Authors


Hopkins, WS More by this author
Woodham, AP More by this author
Plowright, RJ More by this author
Wright, TG More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
The Journal of chemical physics
Volume:
132
Issue:
21
Pages:
214303
Publication date:
2010-06-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:5f9e089b-c276-4f87-96fe-cf1bf6a6a206
Source identifiers:
58993
Local pid:
pubs:58993

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