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A velocity map imaging study of gold-rare gas complexes: Au-Ar, Au-Kr, and Au-Xe.

Abstract:

The ultraviolet photodissociation dynamics of the gold-rare gas atom van der Waals complexes (Au-RG, RG = Ar, Kr, and Xe) have been studied by velocity map imaging. Photofragmentation of Au-Ar and Au-Kr at several wavelengths permits extrapolation to zero of the total kinetic energy release (TKER) spectra as monitored in the Au((2)P(3/2)(o)[5d(10)6p]) fragment channel, facilitating the determination of ground state dissociation energies of D(0)(")(Au-Ar) = 149+/-13 cm(-1) and D(0)(")(Au-Kr) =...

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Publication status:
Published

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Publisher copy:
10.1063/1.3432127

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
The Journal of chemical physics
Volume:
132
Issue:
21
Pages:
214303
Publication date:
2010-06-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:5f9e089b-c276-4f87-96fe-cf1bf6a6a206
Source identifiers:
58993
Local pid:
pubs:58993

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