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Theoretical and experimental study of the ECE mechanism at microring electrodes

Abstract:

Microring electrodes are useful for the investigation of reaction kinetics due to their large perimeter to area ratio and compact nature but have hitherto been limited in application due to the absence of the underpinning theory. In this paper, we apply the conformal mapping technique recently developed by Amatore et al. [C. Amatore, A.I. Oleinick, I.B. Svir, J. Electroanal. Chem. 564 (2004) 245] for the simulation of chronoamperometry at very thin microring electrodes, where an ECE-type mech...

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Publication status:
Published

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Authors


Oleinick, A More by this author
Fisher, AC More by this author
Wadhawan, JD More by this author
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Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
578
Issue:
2
Pages:
289-299
Publication date:
2005-05-01
DOI:
ISSN:
0022-0728
URN:
uuid:5ebe04f1-be8e-4ee8-acbf-ca4b91a0fde3
Source identifiers:
39523
Local pid:
pubs:39523

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