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Tetrahedral oxyanions in halogen-bonded coordination networks

Abstract:

The deliberate construction of (6,3) networks via halogen bond-driven self-assembly of tetra-n-butylammonium perchlorate, periodate, and perrhenate with 1,4-diiodotetrafluorobenzene is reported. The mononegative oxyanions sit at network nodes and work as tridentate halogen bond (XB) acceptors, the diiodobenzene derivative spaces the nodes and function as a bidentate XB donor, while the ammonium cations occupy the space encircled by the supramolecular (6,3) frames. Mixed crystals wherein two d...

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Publisher copy:
10.1021/cg200840m

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Institution:
University of Oxford
Department:
Oxford, MPLS, Physics
Role:
Author
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Journal:
Crystal Growth and Design
Volume:
11
Issue:
9
Pages:
4220-4226
Publication date:
2011-09-07
DOI:
EISSN:
1528-7505
ISSN:
1528-7483
URN:
uuid:5ea07d3a-670f-4859-84ed-db723874876d
Source identifiers:
319145
Local pid:
pubs:319145
Language:
English

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