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C–H and H–H activation at a di-titanium centre

Abstract:
The reaction of the bis(pentalene)dititanium complex Ti2(μ:η5,η5-Pn†)2 (Pn† = C8H4(1,4-SiiPr3)2) with the N-heterocyclic carbene 1,3,4,5-tetramethylimidazol-2-ylidene results in intramolecular C-H activation of one of the iPr methyl groups of a Pn† ligand and formation of a "tucked-in" bridging hydride complex. The "tuck-in" process is reversed by the addition of hydrogen, which yields a dihydride featuring terminal and bridging hydrides.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1039/c7cc07726b

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ORCID:
0000-0003-0262-9382
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
St Hughs College
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ORCID:
0000-0001-7822-6593
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
53
Issue:
98
Pages:
13117-13120
Publication date:
2017-10-25
Acceptance date:
2017-10-25
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pubs id:
pubs:742514
URN:
uri:5e50e329-0fa8-4aac-b8ba-cd95a7f6fe2b
UUID:
uuid:5e50e329-0fa8-4aac-b8ba-cd95a7f6fe2b
Local pid:
pubs:742514
Language:
English

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