- Abstract:
-
A ring−closing alkene metathesis (RCM) / oxyselenation−selenoxide elimination sequence was established to the sodium salts E- and Z-25 of the originally proposed structure for the recently isolated cytotoxin aruncin B (1), as well as to the sodium salt Z-34 of a related ethyl ether regioisomer; however, none of their corresponding free acids could be obtained. Their acid sensitivity, together with detailed analysis of the spectroscopic data indicated that profound structural revision was nece...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's version
- Files:
-
-
(pdf, 771.4kb)
-
- Publisher copy:
- 10.1002/chem.201702949
-
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- Grant:
- People Programme (Marie Curie Actions) of the European Union’s Seventh Framework Programme (FP7/2007-2013) under REA grant agreement 316955
- Grant:
- Oxford Biomedical Research Centre
- Publisher:
- Wiley-VCH Verlag Publisher's website
- Journal:
- Chemistry - A European Journal Journal website
- Volume:
- 23
- Issue:
- 65
- Pages:
- 16525–16534
- Publication date:
- 2017-10-30
- Acceptance date:
- 2017-08-14
- DOI:
- EISSN:
-
1521-3765
- ISSN:
-
0947-6539
- Pubs id:
-
pubs:718301
- URN:
-
uri:5db82ae5-b006-44c3-ab99-73f8ed591460
- UUID:
-
uuid:5db82ae5-b006-44c3-ab99-73f8ed591460
- Local pid:
- pubs:718301
- Paper number:
- 65
- Copyright holder:
- Ribaucourt et al.
- Copyright date:
- 2017
- Notes:
-
Copyright © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Journal article
Aruncin B: synthetic studies, structural reassignment and biological evaluation
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