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Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]

Abstract:
Addition of H2 to the precursor [Rh(Cyp2P(CH2)2PCyp2)(η2 :η2 -C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2P(CH2)2PCyp2)(η2 :η2 -C7H12)][BArF 4] by a single-crystal to single–crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1021/acs.organomet.6b00645

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Department:
Oxford, MPLS, Chemistry
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Oxford, MPLS, Chemistry
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Oxford, MPLS, Chemistry
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Oxford, MPLS, Chemistry
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Publisher:
American Chemical Society Publisher's website
Journal:
Organometallics Journal website
Publication date:
2016-09-23
Acceptance date:
2016-09-19
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Pubs id:
pubs:644339
URN:
uri:5d4a4d7f-5c3c-407d-a662-8c73ea0036b1
UUID:
uuid:5d4a4d7f-5c3c-407d-a662-8c73ea0036b1
Local pid:
pubs:644339

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