- Abstract:
- Addition of H2 to the precursor [Rh(Cyp2P(CH2)2PCyp2)(η2 :η2 -C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2P(CH2)2PCyp2)(η2 :η2 -C7H12)][BArF 4] by a single-crystal to single–crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's version
- Files:
-
-
(pdf, 1.3MB)
-
- Publisher copy:
- 10.1021/acs.organomet.6b00645
-
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- Grant:
- EP/M024210, EP/K035908, EP/K035681
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Organometallics Journal website
- Publication date:
- 2016-09-23
- Acceptance date:
- 2016-09-19
- DOI:
- EISSN:
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1520-6041
- ISSN:
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0276-7333
- Pubs id:
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pubs:644339
- URN:
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uri:5d4a4d7f-5c3c-407d-a662-8c73ea0036b1
- UUID:
-
uuid:5d4a4d7f-5c3c-407d-a662-8c73ea0036b1
- Local pid:
- pubs:644339
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
- © 2016 American Chemical Society. ACS AuthorChoice - This is an open access article published under a Creative Commons Attribution (CC-BY) License.
Journal article
Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]
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+ Engineering and Physical Sciences Research Council
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